Most experiments were performed on polycrystalline ice with various grain sizes, which may not perfectly represent single-crystal ice behavior. Also, the grain boundary effect is not quantified.
Correlation, not causation
While experimental observations suggest a correlation between ice flexoelectricity and thunderstorm charging, there is no definitive causal link established. Other factors may contribute to this phenomenon.
The experimental setup involves electrodes, which may induce surface effects different from the behavior of free ice surfaces.
Oversimplification of the model
The model simplifies complex collision dynamics by ignoring many real-world factors like air resistance, particle shape irregularities, and non-uniform temperature distributions.
The calculations assume pure ice. However, natural ice contains impurities which can significantly alter its properties and potentially influence surface ferroelectricity and charge transfer mechanisms.
While the model calculates the upper bound of transferred charge, it doesn't fully explain the charge distribution after separation, which involves trapping mechanisms and metastable deformation states.