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A generalised, multi-phase-field theory for dissolution-driven stress corrosion cracking and hydrogen embrittlement

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Paper Summary

Paperzilla title
Dissolving the Mystery of Stress Corrosion Cracking: A Multi-Phase-Field Approach

This paper introduces a new multi-phase-field theory to model stress corrosion cracking (SCC), combining hydrogen embrittlement and material dissolution effects. It successfully predicts SCC behavior across various environments and loading conditions, showing how pits and other defects can accelerate corrosion, and how initially dissolution-driven cracks can become hydrogen-dominated over time.

Explain Like I'm Five

Scientists figured out how cracks in metal get worse when the metal slowly gets eaten away and invisible hydrogen gas makes it weak. They found that this "eating away" can start the crack, but then the hydrogen makes it much worse.

Possible Conflicts of Interest

None identified

Identified Limitations

Uncertainty in Hydrogen Degradation Parameters
The reliance on parameters like trap binding energies introduces uncertainties in hydrogen degradation predictions, hindering fully predictive estimations.
Neglecting Plastic Strain Gradients
Neglecting plastic strain gradients in certain analyses may lead to less accurate stress and hydrogen peak predictions near stress concentrators.
Assumption of Small Concentration Gradients
The assumption of small concentration gradients at the interface may not always hold true, potentially affecting the accuracy of fracture predictions.

Rating Explanation

This paper presents a novel generalized theory for stress corrosion cracking, incorporating both hydrogen embrittlement and dissolution mechanisms. The multi-phase-field approach allows for capturing complex interactions between different physical processes involved in SCC. The model is validated against experimental data and provides new insights into the transition between different SCC mechanisms. While some limitations exist, such as uncertainties in hydrogen degradation parameters, the overall methodology is strong and the findings are significant.

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Topic Hierarchy

Subfield: Metals and Alloys

File Information

Original Title: A generalised, multi-phase-field theory for dissolution-driven stress corrosion cracking and hydrogen embrittlement
Uploaded: July 14, 2025 at 05:24 PM
Privacy: Public